Stratospheric solar geoengineering (SG) would impact ozone by heterogeneous chemistry. Evaluating these risks and methods to reduce them will require both laboratory and modeling work. Prior model-only work showed that CaCO₃ particles would reduce, or even reverse ozone depletion. We reduce uncertainties in ozone response to CaCO₃ via experimental determination of uptake coefficients and model evaluation. Specifically, we measure uptake coefficients of HCl and HNO₃ on CaCO₃ as well as HNO₃ and ClONO₂ on CaCl₂ at stratospheric temperatures using a flow tube setup and a flask experiment that determines cumulative long-term uptake of HCl on CaCO₃. We find that particle ageing causes significant decreases in uptake coefficients on CaCO₃. We model ozone response incorporating the experimental uptake coefficients in the AER-2D model. With our new empirical reaction model, the global mean ozone column is reduced by up to 3%, whereas the previous work predicted up to 27% increase for the same SG scenario. This result is robust under our experimental uncertainty and many other assumptions. We outline systematic uncertainties that remain and provide three examples of experiments that might further reduce uncertainties of CaCO₃ SG. Finally, we highlight the importance of the link between experiments and models in studies of SG.

Solar Radiation Modification (SRM) reduces the CO₂‐induced change to the mean global hydrological cycle disproportionately more than it reduces the CO₂‐induced increase in mean surface temperature. Thus if SRM were used to offset all CO₂‐induced mean warming, global‐mean precipitation would be less than in an unperturbed climate. Here we show that the mismatch between the mean hydrological effects of CO₂ and SRM may partly be alleviated by spectrally tuning the SRM intervention (reducing insolation at some wavelengths more than others). By concentrating solar dimming at near‐infrared wavelengths, where H₂O has strong absorption bands, the direct effect of CO₂ on the tropospheric energy budget can be offset, which minimizes perturbations to the mean hydrological cycle. Idealized cloud‐resolving simulations of radiative‐convective equilibrium confirm that spectrally‐tuned SRM can simultaneously maintain mean surface temperature and precipitation at their unperturbed values even as large quantities of CO₂ are added to the atmosphere.

Solar geoengineering appears capable of reducing climate change and the associated risks. In part because it would be global in effect, the governance of solar geoengineering is a central concern. The Earth System Governance (ESG) Project includes many researchers who, to varying degrees, utilize a common vocabulary and research framework. Despite the clear mutual relevance of solar geoengineering and ESG, few ESG researchers have considered the topic in substantial depth. To stimulate its sustained uptake as a subject within the ESG research program, we identify significant contributions thus far by ESG scholars on the subject of solar geoengineering governance and survey the wider solar geoengineering governance literature from the perspective of the new ESG research framework. Based on this analysis, we also suggest specific potential lines of inquiry that we believe are ripe for research by ESG scholars: nonstate actors’ roles, polycentricity, public engagement and participation, and the Anthropocene.